An enantiopure N,N,S scorpionate ligand derived from (+)-camphor.
نویسندگان
چکیده
Reductive S-S bond cleavage of a disulfide precursor obtained from a pyridine-catalyzed Peterson-type reaction starting from camphorpyrazole , thionyl chloride and 2-methyl-2-(methyldithio)propionaldehyde yields 2,2'-bis(camphorpyrazol-1-yl)-2-methylpropane-2-thiol (HSiprbpm3cam, ); the first zinc complexes bearing this ligand exhibit kappa3 coordination of the ligand.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 2 شماره
صفحات -
تاریخ انتشار 2009